18. Argon

Argon has three full electron shells. With 6 electrons in a 3p orbital, argon is believed to achieve stability with octahedral symmetry, and its 3s electrons can unhybridize and return to their preferred spherical di-electron state. It is proposed in the theory of Sub-Quantum Chemistry, however, that argon is more stable with full shells containing 4 di-electrons in sp3-hybridization (shown below).

This high degree of symmetry, with all electrons paired, renders argon, like helium and neon, unreactive.

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As a reminder, the outer spheres in these diagrams are only meant to indicate the directions of the orbital lobes. These lobes are not spheres. Only s-orbitals are spherical. It is noteworthy that the tetrahedral arrangements in adjacent shells align antiparallel to each other. This places the maximum distance between electron density on adjacent shells in order to minimize electron repulsion.

As in the case of neon, if we consider the tetrahedral full-shell configuration, then argon will have a nested spherical tetrahedral orbital arrangement, the 2nd and 3rd shells each containing four di-electrons (below, right).

Neon’s tetrahedral sp3 orbitals
Argon’s antiparallel nested tetrahedra

Intuitively, this seems more stable as it involves a greater degree of field cancellation than a full p-orbital with a single electron occupying each lobe. The entire shell contains electron density. It is highest at the center of the face of each orbital and decreases to lowest density at the nodal regions that divide the orbitals. Together, all atomic orbitals constitute a single, phase-locked, resonant, coherent, harmonic, stationary wave.

As mentioned above, the nested tetrahedral shells align in an opposite or antiparallel fashion. The reason this geometry is so stable for electrons is that the region of lowest electron density on one shell lines up with the region of maximum electron density on the adjacent shell, minimizing repulsion. In the diagram (below), the vertex represents where the nodes between orbitals intersect. This is a point of lowest electron density. It lies directly over the center of the face of the orbital beneath it, which is the point of highest electron density in that orbital. This is therefore the lowest energy state that nested tetrahedral shells can achieve.

Argon’s antiparallel nested tetrahedra (left), and with one outer orbital raised (right)

RETURN to the Periodic Table or COMPARE to Neon.

SEE OTHER NOBLE GASES: Helium, Neon, Argon, Krypton, Xenon